2.4 C—H Functionalization Catalyzed by Cobalt(III)/Cp* and Related Complexes
Book
Editor: Yoshikai, N.
Title: Base-Metal Catalysis 2
Print ISBN: 9783132455030; Online ISBN: 9783132455054; Book DOI: 10.1055/b000000440
1st edition © 2023 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Type: Multivolume Edition
Abstract
![](https://www.thieme-connect.de/media/10.1055-b000000440/thumbnails/a_225yod.jpg)
Cobalt(III) catalysts bearing a pentamethylcyclopentadienyl ligand are widely used for directing-group-assisted C—H functionalization reactions to form C—C and C—heteroatom bonds. This review describes representative examples of such cobalt(III)-catalyzed C—H functionalization reactions, including C(sp2) —H and C(sp3) —H functionalization, as well as enantioselective C—H functionalization.
Key words
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