2.2 Cobalt- and Iron-Catalyzed Hydrosilylation

Z. Cheng; M. Li; Z. Lu 

Abstract

The hydrosilylation of readily available alkenes and alkynes represents an atom-economic and straightforward method for the preparation of value-added organosilicon compounds. Among various catalysts, those based on earth-abundant metals such as cobalt and iron demonstrate great potential due to their low cost and toxicity, as well as good catalytic performance. This review discusses recent progress in the cobalt- and iron-catalyzed hydrosilylation of alkenes and alkynes, as well as the sequential double hydrosilylation of alkynes, with an emphasis on the synthetic utility of the methods. The reactivity, regioselectivity, and enantioselectivity can be well-controlled by applying suitable ligands.

Key words

earth-abundant metals - iron catalysis - cobalt catalysis - hydrosilylation - regioselectivity - enantioselectivity - alkenes - alkynes - organosilicon

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