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Maiti, D. : 2023 Science of Synthesis, 2023/4: Cross-Dehydrogenative Coupling DOI: 10.1055/sos-SD-240-00005
Cross-Dehydrogenative Coupling

5 (Het)Arene/(Het)Arene Cross-Dehydrogenative Coupling for C(sp2)—C(sp2) Bond Formation

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Buch

Herausgeber: Maiti, D. 

Autoren: Adak, L. ; Ali, W.; Aravindan, N.; Arun, V. ; Baidya, M. ; Besset, T. ; Brocksom, T. J. ; Chen, T. ; Chowdhury, D.; de Oliveira, K. T. ; De Sarkar, S. ; Escudero, J. ; Faisca Phillips, A. M. ; Fukuta, T.; Ghosh, S. ; Ghosh, T.; Guedes da Silva, M. F. C. ; Guin, S.; Han, L.-B. ; Huang, C.-Y. ; Iwasaki, T. ; Jeganmohan, M. ; Jha, N. ; Kakiuchi, F. ; Kambe, N.; Kanai, M. ; Kang, H. ; Kapur, M. ; Khandelia, T. ; Kochi, T. ; Koner, M.; Li, C.; Li, C.-J. ; Li, X. ; Logeswaran, R.; Maes, B. U. W. ; Maiti, D. ; Martins, G. M. ; Miyabe, H. ; Patel, B. K. ; Pombeiro, A. J. L. ; Ranu, B. C. ; Saha, S. K. ; Sambiagio, C. ; Silva, R. C. ; Song, Q. ; Zimmer, G. C. 

Titel: Cross-Dehydrogenative Coupling

Print ISBN: 9783132455245; Online ISBN: 9783132455269; Buch-DOI: 10.1055/b000000640

1st edition © 2023. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

Science of Synthesis Reference Libraries



Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

Among the various strategies for C—C bond formation, cross-dehydrogenative coupling (CDC) reactions form an integral class, primarily due to their step- and atom-economic nature. With dihydrogen as the only side-product, this method couples two unmodified C—H bonds, thereby avoiding the need for prefunctionalization of substrates. This chapter focuses exclusively on transition-metal-catalyzed C(sp2)—C(sp2) bond-forming CDC reactions between arenes/hetarenes. The most viable methods, leading to the facile syntheses of biaryl scaffolds, have been assembled, thereby providing a platform for easy access to a wide variety of arene or hetarene skeletons.

Schlüsselwörter

C—C bond formation - cross-dehydrogenative coupling - unmodified C—H bonds - transition-metal catalysis - arenes - hetarenes - biaryls
 
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