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Maiti, D. : 2023 Science of Synthesis, 2023/4: Cross-Dehydrogenative Coupling DOI: 10.1055/sos-SD-240-00034
Cross-Dehydrogenative Coupling

7 Alkene/Alkene Cross-Dehydrogenative Coupling for C(sp2)—C(sp2) Bond Formation

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Editor: Maiti, D. 

Authors: Adak, L. ; Ali, W.; Aravindan, N.; Arun, V. ; Baidya, M. ; Besset, T. ; Brocksom, T. J. ; Chen, T. ; Chowdhury, D.; de Oliveira, K. T. ; De Sarkar, S. ; Escudero, J. ; Faisca Phillips, A. M. ; Fukuta, T.; Ghosh, S. ; Ghosh, T.; Guedes da Silva, M. F. C. ; Guin, S.; Han, L.-B. ; Huang, C.-Y. ; Iwasaki, T. ; Jeganmohan, M. ; Jha, N. ; Kakiuchi, F. ; Kambe, N.; Kanai, M. ; Kang, H. ; Kapur, M. ; Khandelia, T. ; Kochi, T. ; Koner, M.; Li, C.; Li, C.-J. ; Li, X. ; Logeswaran, R.; Maes, B. U. W. ; Maiti, D. ; Martins, G. M. ; Miyabe, H. ; Patel, B. K. ; Pombeiro, A. J. L. ; Ranu, B. C. ; Saha, S. K. ; Sambiagio, C. ; Silva, R. C. ; Song, Q. ; Zimmer, G. C. 

Title: Cross-Dehydrogenative Coupling

Print ISBN: 9783132455245; Online ISBN: 9783132455269; Book DOI: 10.1055/b000000640

1st edition © 2023. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

Conjugated dienes are not only synthetically versatile but are also often found in natural products and bioactive compounds, and various methods have been developed for the stereo- and regioselective synthesis of 1,3-diene structures. Recently, much attention has been paid to transition-metal-catalyzed cross-dehydrogenative coupling (CDC) reactions between alkenes, because they enable the synthesis of 1,3-dienes in few steps from readily available molecules, thus providing atom-economical, environmentally benign synthetic methods. This chapter briefly describes representative examples of alkene CDC reactions between two different alkenes.

Key words

C—H bond activation - C—C bond formation - cross-dehydrogenative coupling - 1,3-dienes - β-hydride elimination - acrylates - acrylamides - acrylic acids - vinyl ketones - vinylphosphonates - vinyl sulfones - alkenyl ethers - enamines - ketene dithioacetals - aromatic alkenes - directing groups - high-valent transition-metal catalysts
 
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