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Maiti, D. : 2023 Science of Synthesis, 2023/4: Cross-Dehydrogenative Coupling DOI: 10.1055/sos-SD-240-00107
Cross-Dehydrogenative Coupling

4 Cross-Dehydrogenative Coupling Involving Alkynes for C(sp2)—C(sp) Bond Formation

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Buch

Herausgeber: Maiti, D. 

Autoren: Adak, L. ; Ali, W.; Aravindan, N.; Arun, V. ; Baidya, M. ; Besset, T. ; Brocksom, T. J. ; Chen, T. ; Chowdhury, D.; de Oliveira, K. T. ; De Sarkar, S. ; Escudero, J. ; Faisca Phillips, A. M. ; Fukuta, T.; Ghosh, S. ; Ghosh, T.; Guedes da Silva, M. F. C. ; Guin, S.; Han, L.-B. ; Huang, C.-Y. ; Iwasaki, T. ; Jeganmohan, M. ; Jha, N. ; Kakiuchi, F. ; Kambe, N.; Kanai, M. ; Kang, H. ; Kapur, M. ; Khandelia, T. ; Kochi, T. ; Koner, M.; Li, C.; Li, C.-J. ; Li, X. ; Logeswaran, R.; Maes, B. U. W. ; Maiti, D. ; Martins, G. M. ; Miyabe, H. ; Patel, B. K. ; Pombeiro, A. J. L. ; Ranu, B. C. ; Saha, S. K. ; Sambiagio, C. ; Silva, R. C. ; Song, Q. ; Zimmer, G. C. 

Titel: Cross-Dehydrogenative Coupling

Print ISBN: 9783132455245; Online ISBN: 9783132455269; Buch-DOI: 10.1055/b000000640

1st edition © 2023. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

Science of Synthesis Reference Libraries



Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

Cross-dehydrogenative coupling reactions represent one of the most environmentally friendly and atom-economic strategies to achieve carbon–carbon or carbon–heteroatom bond formation from non-prefunctionalized substrates, formally producing only dihydrogen as waste. Using terminal alkynes as one of the coupling partners in cross-dehydrogenative couplings, the sustainable synthesis of a myriad of alkynylated compounds is possible. In this review, the major advances in cross-dehydrogenative couplings involving alkynes are covered, with a focus on the formation of C(sp2)—C(sp) bonds, leading to alkynylated arenes, 1,3-enynes, and ynone derivatives. Synthetic strategies, reaction conditions, and the scope of each method are critically discussed, from early developments to date.

Schlüsselwörter

cross-dehydrogenative coupling - transition-metal catalysis - alkynes - cross coupling - alkynylation - C—H activation - radical chemistry - C—C bond formation - heterocycles - carbonyl compounds - aromatic compounds - 1,3-enynes
 
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