18 Heteroatom—Heteroatom Bond Formation through Cross-Dehydrogenative Coupling

Abstract

Cross-dehydrogenative coupling between E—H bonds and Z—H bonds, where E and Z are heteroatoms, can be considered as a green approach for the construction of chemical bonds. Since it avoids the need for prefunctionalization of the starting materials, this type of transformation can shorten synthetic routes and increase the total atom efficiency. In this context, such reactions are recognized as an efficient alternative to classical cross-coupling reactions. During the past decades, the cross-dehydrogenative coupling strategy has been widely used for synthesizing various target functional molecules, and great achievements have been made in carbon—carbon bond formation. In recent years, cross-dehydrogenative coupling has also been employed to construct heteroatom—heteroatom bonds; this review covers advances in this field, with a focus on methods for the formation of phosphorus—heteroatom and sulfur—heteroatom bonds

Key words

cross-dehydrogenative coupling - oxidative coupling - hydrogen release - heteroatom chemistry - atom economy - step economy - sustainable chemistry - catalysis

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