Synthesis of N², N⁶-bis(5-methylthiazol-2-yl)pyridine-2,6-dicarboxamide fluoroscent sensor for detection of Cu²⁺ and Ni²⁺ Ions

Abstract

This article reports an amide based Chemosensor used for selective detection of divalent Cu⁺² and Ni⁺² ions via Fluorescence turn off. The selective sensing ability of Chemosensor was investigated in presence of different metal ions Mg²⁺, Ag⁺, Fe²⁺, K⁺, Cu²⁺, Ni²⁺, Hg²⁺, Pb²⁺, Mn²⁺, Pd²⁺, Cd²⁺ and Mn³⁺ as competitive ions. The receptor i. e. Chemosensor formed complexes with metal ions in 1:1 stoichiometric ratio. The detection limit and binding constant calculated as 1.92×10^–4 and 1.4×10^–4 M and 2.16×10³ M⁻¹ and 3.09×10³ M⁻¹ for Cu²⁺ and Ni²⁺ions respectively. The complexes were characterized by UV/visible, FT-IR, ¹³C NMR and ¹H NMR spectroscopy. Further the structure and Crystallinity were calculated by P-XRD spectral analysis. The crystallinity found to be 65.27 and 67.87% respectively

Key words

fluorescence quenching - chemosensor - Cu²⁺ and Ni²⁺ ions detection - binding constant chemistry - screening - toxicology

Publication History

Received: 27 August 2020

Accepted: 26 October 2020

Article published online:
22 April 2021

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