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DOI: 10.1055/a-1325-4092
Catalytic Asymmetric Osmium-Free Dihydroxylation of Alkenes
This work is supported by National Natural Science Foundation of China (Grant No. 21772183, 22071230), Fundamental Research Funds for the Central Universities (WK2060190086), ‘1000-Youth Talents Plan’ start-up funding, as well as University of Science and Technology of China.
Abstract
Asymmetric dihydroxylation of alkenes is one of the cornerstone reactions in organic synthesis, providing a direct entry to optically active vicinal diols, which are not only a subunit in natural products but also versatile building blocks. In recent years, considerable progress in catalytic asymmetric osmium-free dihydroxylation has been achieved. This short review presents a concise summary of the reported methods of catalytic asymmetric osmium-free dihydroxylation.
1 Introduction
2 Iron-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes
3 Manganese-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes
4 Palladium/Gold Bimetallic Nanocluster-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes
5 Enzyme-Catalyzed Asymmetric anti-Dihydroxylation of Alkenes
6 Amine-Catalyzed Asymmetric Formal anti-Dihydroxylation of Enals
7 Diselenide-Catalyzed anti-Dihydroxylation of Alkenes
8 Molybdenum-Catalyzed Asymmetric anti-Dihydroxylation of Allylic Alcohols
9 Phase-Transfer-Catalyzed Asymmetric Dihydroxylation of α-Aryl Acrylates
10 Conclusion
Publication History
Received: 27 October 2020
Accepted after revision: 30 November 2020
Accepted Manuscript online:
30 November 2020
Article published online:
29 January 2021
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For reviews on osmium-catalyzed asymmetric dihydroxylation, see: