Synthesis, Table of Contents Synthesis 2021; 53(09): 1654-1662DOI: 10.1055/a-1336-5720 paper Oxidative C–H Acyloxylation of Acetone with Carboxylic Acids under Iodine Catalysis Xiao-Yu Zhou∗ , Xia Chen Recommend Article Abstract Buy Article All articles of this category Abstract Iodine-catalyzed oxidative C(sp3)–H acyloxylation of acetone with carboxylic acids has been developed. The method employs iodide as catalyst and sodium chlorite as oxidant. Substituted benzoic acids, naphthoic acids and heteroaromatic carboxylic acids can be used, and 2-oxopropyl carboxylates are obtained with good to excellent yields. Key words Key wordsiodine - oxidative C–H functionalization - acetone - carboxylic acids - carboxylates Full Text References References and Notes 1a Cavallo G, Metrangolo P, Milani R, Pilati T, Priimagi A, Resnati G, Terraneo G. Chem. Rev. 2016; 116: 2478 1b Heinen F, Engelage E, Dreger A, Weiss R, Huber SM. Angew. Chem. Int. 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