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Synthesis 2021; 53(09): 1654-1662
DOI: 10.1055/a-1336-5720
DOI: 10.1055/a-1336-5720
paper
Oxidative C–H Acyloxylation of Acetone with Carboxylic Acids under Iodine Catalysis
The work was supported by the Foundation of Guizhou Educational Committee (Grant No. qianjiaohe KY zi [2019] 081) and the Natural Science Foundation of Guizhou Province (Grant No. qiankehejichu [2018] number 1141)
Abstract
Iodine-catalyzed oxidative C(sp3)–H acyloxylation of acetone with carboxylic acids has been developed. The method employs iodide as catalyst and sodium chlorite as oxidant. Substituted benzoic acids, naphthoic acids and heteroaromatic carboxylic acids can be used, and 2-oxopropyl carboxylates are obtained with good to excellent yields.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1336-5720.
- Supporting Information
Publikationsverlauf
Eingereicht: 04. November 2020
Angenommen nach Revision: 14. Dezember 2020
Accepted Manuscript online:
14. Dezember 2020
Artikel online veröffentlicht:
12. Januar 2021
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