Homogeneous Palladium-Catalyzed Selective Reduction of 2,2′-Biphenols Using HCO2H as Hydrogen Source

Ruoling Li; Chenchen Li; Wen Yang; Wanxiang Zhao

doi:10.1055/a-1337-5153

Synthesis, Inhaltsverzeichnis

Synthesis 2021; 53(09): 1605-1618
DOI: 10.1055/a-1337-5153

paper

Homogeneous Palladium-Catalyzed Selective Reduction of 2,2′-Biphenols Using HCO₂H as Hydrogen Source

Ruoling Li

,

Chenchen Li

,

Wen Yang∗

,

Wanxiang Zhao ∗

Abstract

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Abstract

An efficient homogeneous palladium-catalyzed selective deoxygenation of 2,2′-biphenols by reduction of aryl triflates with HCO₂H as the hydrogen source is reported. This protocol complements the current method based on heterogeneous Pd/C-catalyzed hydrogenation with hydrogen gas. This process provided the reduction products in good to excellent yields, which could be readily converted to various synthetically useful molecules, especially ligands for catalytic synthesis.

Key words

palladium - homogeneous catalysis - 2,2′-biphenols - reduction - formic acid

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