Synthesis of Unsymmetrically Substituted Tetraphenylenes through Palladium-Catalyzed C(sp2)–H Activation

Bin Wan; Yanghui Zhang

doi:10.1055/a-1416-9737

Synthesis, Table of Contents

Synthesis 2021; 53(18): 3299-3306
DOI: 10.1055/a-1416-9737

special topic

Bond Activation – in Honor of Prof. Shinji Murai

Synthesis of Unsymmetrically Substituted Tetraphenylenes through Palladium-Catalyzed C(sp²)–H Activation

Bin Wan

,

Yanghui Zhang∗

Abstract

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Abstract

An efficient protocol for the palladium-catalyzed cross-coupling reaction of 2-iodobiphenyls with biphenylene has been developed through C–H activation. The reaction provides a simple and efficient method for the synthesis of unsymmetrically substituted tetraphenylenes.

Key words

palladium catalysis - C–H activation - tetraphenylenes - cross-coupling - unsymmetrical substitution

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References

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Supplementary Material

Supporting Information