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Synthesis 2021; 53(23): 4313-4326
DOI: 10.1055/a-1538-8344
DOI: 10.1055/a-1538-8344
short review
Application of Industrially Relevant HydroFluoroOlefin (HFO) Gases in Organic Syntheses
The authors thank the support of National Research, Development and Innovation Office (Grant No. K132077), ELTE Thematic Excellence Programme 2020 Supported by National Research, Development and Innovation Office – TKP2020-IKA-05, and UNKP-20-3 New National Excellence Program of the Ministry for Innovation and Technology from the source of the National Research, Development and Innovation Fund.
Abstract
Hydrofluoroolefin (HFO) gases are state-of-the-art cooling agents with widespread household and industrial applications. Considering their structural benefits these fluorous feedstocks have gained the attention of organic chemists in the last couple of years. In this short review we summarized the existing synthetic transformations of these gaseous starting material and present their applicability in the synthesis of fluorine-containing organic molecules, which have potential importance as building blocks and reagents for diverse syntheses.
1 Introduction
2 Addition Reactions
3 Substitutions
4 Organometallic Chemistry
4.1 Organolithium Compounds
4.2 Organometallic Complexes
4.3 Silicon Organic Chemistry
4.4 Boron Organic Chemistry
4.5 Palladium-Catalyzed Transformations
4.6 Metathesis
4.7 Hydroesterification, Hydroformylation
5 Conclusions
Publication History
Received: 09 April 2021
Accepted after revision: 28 June 2021
Accepted Manuscript online:
28 June 2021
Article published online:
11 August 2021
© 2021. Thieme. All rights reserved
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