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Synthesis 2022; 54(01): 184-198
DOI: 10.1055/a-1561-5508
DOI: 10.1055/a-1561-5508
paper
Environmentally Friendly and Recyclable CuCl2-Mediated C–S Bond Coupling Strategy Using DMEDA as Ligand, Base, and Solvent
This work was financially supported by the Natural Science Foundation of Shandong Province (ZR2019QB022), the National Natural Science Foundation of China (21871125) and the Doctoral Scientific Research Startup Foundation of Liaocheng University (No. 31805403).
Abstract
Simple reaction conditions and recyclable reagents are crucial for environmentally friendly industrial applications. An environment-friendly, recyclable and economic strategy was developed to synthesize diaryl chalcogenides by the CuCl2-catalyzed C–S bond-formation reaction via iodobenzenes and benzenethiols/1,2-diphenyldisulfanes using N,N′-dimethylethane-1,2-diamine (DMEDA) as ligand, base, and solvent. For these reactions, especially the reactions of diiodobenzenes and aminobenzenethiols/disulfanediyldianilines, a range of substrates are compatible and give the corresponding products in good to excellent yields. Both of the reagents in the catalytic system (CuCl2/DMEDA) are inexpensive, conveniently separable, and recyclable for more than five cycles.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1561-5508.
- Supporting Information
Publication History
Received: 02 June 2021
Accepted after revision: 29 July 2021
Accepted Manuscript online:
29 July 2021
Article published online:
09 September 2021
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