Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks

Jonas Everaert; Maarten Debruyne; Flore Vanden Bussche; Kristof Van Hecke; Thomas S. A. Heugebaert; Pascal Van Der Voort; Veronique Van Speybroeck; Christian V. Stevens

doi:10.1055/a-1626-5749

Synthesis, Table of Contents

Synthesis 2023; 55(02): 333-340
DOI: 10.1055/a-1626-5749

paper

Special Issue dedicated to Prof. Alain Krief

Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks

Jonas Everaert

^aSynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, 9000 Ghent, Belgium

,

Maarten Debruyne

^aSynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, 9000 Ghent, Belgium

,

Flore Vanden Bussche

^aSynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, 9000 Ghent, Belgium

^bDepartment of Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium

,

Kristof Van Hecke

^bDepartment of Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium

,

Thomas S. A. Heugebaert

^aSynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, 9000 Ghent, Belgium

,

Pascal Van Der Voort

^bDepartment of Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium

,

Veronique Van Speybroeck

^cCenter for Molecular Modeling (CMM), Ghent University, Technologiepark 46, 9052 Zwijnaarde, Belgium

,

Christian V. Stevens ∗

^aSynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, 9000 Ghent, Belgium

› Author Affiliations

Abstract

All articles of this category

Dedicated to Prof. Alain Krief on the occasion of his 80th birthday

Abstract

Covalent triazine frameworks (CTFs) based on polydentate ligands are highly promising supports to anchor catalytic metal complexes. The modular nature of CTFs allows to tailor the composition, structure, and function to its specific application. Access to a broad range of chelating building blocks is therefore essential. In this respect, we extended the current available set of CTF building blocks with new nitrile-functionalized N-heterocyclic ligands. This paper presents the synthesis of the six ligands which vary in the extent of the aromatic system and the denticity. The new building blocks may help in a rational design of enhanced support materials in catalysis.

Key words

N-heterocycles - 1,4-diazadiene ligands - 2,2′-bipyridine - 2,2′-biquinoline - 2,6-bis(benzimidazolyl)pyridine - nitrile building blocks - covalent triazine frameworks

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References

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