Synthesis and Reactions of Borazines

Ishita Neogi; Alex M. Szpilman

doi:10.1055/a-1684-0031

Synthesis, Inhaltsverzeichnis

Synthesis 2022; 54(08): 1877-1907
DOI: 10.1055/a-1684-0031

review

Synthesis and Reactions of Borazines

Ishita Neogi ∗

^aPhotoscience and Photonics Section, Chemical Science and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Thiruvananthapuram, 695019 India, India

^bAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002 India, India

,

Alex M. Szpilman ∗

^cDepartment of Chemical Sciences, Ariel University, 40700000 Ariel, Israel

› Institutsangaben

Abstract

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Abstract

Given the wide array of current applications of borazine-based materials, synthetic access to these compounds is of importance. This review summarizes the many ways of preparing borazines and its carbo-substituted analogues. In addition, the functionalization of borazines is covered. The synthesis of molecules incorporating more than one borazine units as well as aspects of unsymmetrically substituted borazines are not included. The literature has been covered comprehensively until the end of 2020.

1 Introduction: Structure and Properties of Borazine

2 Synthesis of Parent Borazine

3 Synthesis of N-Substituted Borazines

4 Synthesis of B-Halo/B-Halo-N-Substituted Borazines

5 Synthesis of B-Substituted Borazines

6 Synthesis of Polycyclic Borazines Containing One Borazine Ring

7 Modifications or Hydrolysis of the Borazine Ring

8 Borazine Metal Complexes

9 Outlook and Conclusion

Key words

borazine - aromaticity - synthesis - supramolecular chemistry - boron - nitrogen

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Referenzen

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