Applications of Photoredox Catalysis for the Radical-Induced Cleavage of C–C Bonds

Jaro Vanderghinste; Shoubhik Das

doi:10.1055/a-1702-6193

Synthesis, Table of Contents

Synthesis 2022; 54(15): 3383-3398
DOI: 10.1055/a-1702-6193

special topic

Bürgenstock Special Section 2021 – Future Stars in Organic Chemistry

Applications of Photoredox Catalysis for the Radical-Induced Cleavage of C–C Bonds

Jaro Vanderghinste

,

Shoubhik Das ∗

Abstract

All articles of this category

Abstract

Selective cleavage of C–C bonds forms one of the greatest challenges in current organic chemistry, due to the relative strength of these bonds. However, such transformations are an invaluable instrument to break down and construct new carbon–carbon bonds. To achieve this, photochemistry can be used as a tool to generate radicals and induce the cleavage of these bonds due to their high reactivity. This review examines some of the most influential contributions in this field since 2010.

1 Introduction

2 C–C Bond Cleavage

2.1 Homogeneous Catalyst

2.1.1 N-Centered Radical

2.2.2 O-Centered Radical

2.2 Heterogeneous Catalyst

3 C=C Bond Cleavage

3.1 Homogeneous Catalyst

3.2 Heterogeneous Catalyst

4 C≡C Bond Cleavage

4.1 Homogeneous Catalyst

4.2 Heterogeneous Catalyst

5 Conclusion

Key words

photochemistry - radicals - C–C bond cleavage - visible light - homogeneous - heterogeneous

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References

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