Ferrocenephosphonates: Copper-Promoted Synthesis and Further Functionalization

Kmar Abaid; William Erb; Marielle Blot; Thierry Roisnel; Florence Mongin; Soufiane Touil

doi:10.1055/a-1767-3026

Synthesis, Inhaltsverzeichnis

Synthesis 2022; 54(12): 2799-2815
DOI: 10.1055/a-1767-3026

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Ferrocenephosphonates: Copper-Promoted Synthesis and Further Functionalization

Kmar Abaid

^aUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France

^bUniversity of Carthage, Faculty of Sciences of Bizerte, Laboratory of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11), 7021, Jarzouna, Tunisia

,

William Erb ∗

^aUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France

,

Marielle Blot

^aUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France

,

Thierry Roisnel

^aUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France

,

Florence Mongin

^aUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France

,

Soufiane Touil∗

^bUniversity of Carthage, Faculty of Sciences of Bizerte, Laboratory of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11), 7021, Jarzouna, Tunisia

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Abstract

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Abstract

Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferrocenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki–Miyaura cross-coupling reactions are also described to reach original derivatives.

Key words

ferrocene - phosphonates - copper catalysis - cross-coupling - deprotolithiation

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Referenzen

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