Recent Advances to Mediate Reductive Processes of Nitroarenes Using Single-Electron Transfer, Organomagnesium, or Organozinc Reagents

Haoran Zhu; Tom G. Driver

doi:10.1055/a-1792-6579

Synthesis, Table of Contents

Synthesis 2022; 54(14): 3142-3161
DOI: 10.1055/a-1792-6579

short review

Recent Advances to Mediate Reductive Processes of Nitroarenes Using Single-Electron Transfer, Organomagnesium, or Organozinc Reagents

Haoran Zhu

,

Tom G. Driver∗

Abstract

All articles of this category

Abstract

Nitroarenes are readily available compounds that are commonly utilized in reductive processes to form C–NAr bonds via reactive nitrogen intermediates. Recent advances in the development of reductive reactions of nitroarenes using organomagnesium, organozinc, and single-electron transfer reagents are discussed within this short review.

1 Introduction

2 Organomagnesium-Mediated Reductive Reactions of Nitroarenes

3 Organozinc- and Zinc-Mediated Reductive Reactions of Nitroarenes

4 Iodine-Catalyzed Redox Cyclizations of Nitroarenes

5 Titanium(III)-Mediated Reductive Cyclizations

6 Sulfur-Mediated Reductive Reactions of Nitroarenes

7 Alkoxide-Mediated Reductive Reactions of Nitroarenes

8 4,4′-Bipyridine-Mediated Reductive Reactions of Nitroarenes

9 Visible-Light-Driven Reductive Amination Reactions

10 Electrochemical Reductive Reactions

11 Conclusion

Key words

nitroarenes - nitrosoarenes - single-electron transfer - organomagnesium - organozinc - titanium(III) - reduction

Full Text

References

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