Poly(ethylene glycol) Dimethyl Ethers (PEGDME): Efficient and Recyclable Solvents for Aryne-Involved Reactions

Shweta Rai; Polasani Samatha; Ramunaidu Addipilli; Prathama S. Mainkar; Prabhakar Sripadi; Raju Adepu; Srivari Chandrasekhar

doi:10.1055/a-1846-5598

Synthesis, Inhaltsverzeichnis

Synthesis 2022; 54(22): 5026-5034
DOI: 10.1055/a-1846-5598

special topic

Aryne Chemistry in Synthesis

Poly(ethylene glycol) Dimethyl Ethers (PEGDME): Efficient and Recyclable Solvents for Aryne-Involved Reactions

Shweta Rai

^aDepartment of Organic Synthesis and Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

^cAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

,

Polasani Samatha

^aDepartment of Organic Synthesis and Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

,

Ramunaidu Addipilli

^bCentre for Mass Spectrometry, Department of Analytical & Structural Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

^cAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

,

Prathama S. Mainkar

^aDepartment of Organic Synthesis and Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

^cAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

,

Prabhakar Sripadi

^bCentre for Mass Spectrometry, Department of Analytical & Structural Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

^cAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

,

Raju Adepu

^aDepartment of Organic Synthesis and Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

^cAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

,

Srivari Chandrasekhar ∗

^aDepartment of Organic Synthesis and Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India

^cAcademy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

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Abstract

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Abstract

A variety of aryne reactions are demonstrated in poly(ethylene glycol) dimethyl ethers (PEGDMEs) as solvents without the need of any additive. The reactions proceed efficiently and good yields of the desired products are observed with PEGDME. Further, the advantage of being able to recycle PEG solvents is demonstrated in this work.

Key words

aryne reactions - poly(ethylene glycol) dimethyl ether - metal complexes - recyclable solvent

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