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CC BY-NC-ND 4.0 · Organic Materials 2022; 4(02): 28-35
DOI: 10.1055/a-1873-5360
Organic Materials in Electronics
Original Article

Fluorene-Modified Zinc Porphyrin as Low-Cost Hole-Transporting Material for Efficient Perovskite Solar Cells

Yu-Duan Wang 
a   Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. of China
b   School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
,
Jiang-Yang Shao 
a   Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. of China
,
Zhong-Rui Lan 
a   Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. of China
b   School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
,
Yu-Wu Zhong 
a   Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. of China
b   School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
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Abstract

The potential of porphyrin derivatives as hole-transporting materials (HTMs) for perovskite solar cells (PSCs) has been demonstrated. The structural engineering of porphyrin HTMs provides an important means for further improvement of the performance of PSCs. Herein, a zinc-porphyrin derivative (ZnP-FL) decorated with four fluorene-terminated triarylamines is presented. The lab synthesis cost of ZnP-FL is estimated to be around $32.2/g. It exhibits good charge-transport ability and thermal stability. A high power conversion efficiency (PCE) of 19.31% is achieved by using ZnP-FL HTM (V oc = 1.08 V; J sc = 24.08 mA · cm−2), which is distinctly higher than that of a control HTM without the fluorene groups (PCE = 17.75%; V oc = 0.97 V; J sc = 24.04 mA · cm−2). This performance enhancement is mainly attributed to the improved open-circuit voltage, which benefits from the stabilized HOMO level of ZnP-FL. In addition, the porphyrin HTM-based PSCs show superior air and thermal stability to the device with the standard HTM spiro-OMeTAD. These results demonstrate that the low-cost and easily accessible porphyrin derivatives are promising HTMs for efficient and stable PSCs.

Key words

hole-transporting materials - porphyrin derivatives - perovskite solar cells - stability

Supporting Information



Publikationsverlauf

Eingereicht: 29. April 2022

Angenommen nach Revision: 09. Juni 2022

Accepted Manuscript online:
10. Juni 2022

Artikel online veröffentlicht:
29. Juni 2022

© 2022. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)

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