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Synlett 2022; 33(16): 1607-1618
DOI: 10.1055/a-1874-3463
DOI: 10.1055/a-1874-3463
account
No Sacrifice No Gain: Construction of Cleavable Bridged Macrobicyclic Olefins for Precision Polymers
This research was supported by National Natural Science Foundation of China (Grant No. 21971037) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.
Abstract
Olefin metathesis polymerization has commanded great attention as a versatile method for preparing macromolecular materials with advanced architectures and functions in academia and industry. This Account summarizes our endeavors directed towards the preparation of various functional polymers by using olefin metathesis polymerization strategies in particular acyclic diene metathesis (ADMET) polymerization and ring-opening metathesis polymerization (ROMP), during the last ten years. In addition, the merits and limitations of ADMET polymerization and ROMP techniques are also demonstrated and compared. Notably, this Account highlights our recently developed sequence-controlled ROMP strategy for production of precision polymers in a regio-/stereoselective manner, the rollercoaster journey for the evolution of a macrobicyclic olefin system containing a sacrificial silyloxide bridge is described in detail.
1 Introduction
2 Olefin Metathesis Step-Growth Polymerization Approaches
3 Olefin Metathesis Chain-Growth Polymerization Approaches
4 ROMP of Cleavable Bridged Macrobicyclic Olefins
5 Conclusion
Key words
olefin metathesis polymerization - precision polymer - sequence control - acyclic diene metathesis polymerization - macrobicyclic olefin - ring-opening metathesis polymerizationSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1874-3463.
- Supporting Information
Publication History
Received: 28 April 2022
Accepted after revision: 13 June 2022
Accepted Manuscript online:
13 June 2022
Article published online:
07 July 2022
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