State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes

Wei-Sheng Huang; Qing Wang; Hua Yang; Li-Wen Xu

doi:10.1055/a-1929-4890

Synthesis, Table of Contents

Synthesis 2022; 54(24): 5400-5408
DOI: 10.1055/a-1929-4890

short review

State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes

Wei-Sheng Huang

^aCollege of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China

^bKey Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, and Key Laboratory of Organosilicon Material Technology of Zhejiang Province, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China

,

Qing Wang

^aCollege of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China

,

Hua Yang

^bKey Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, and Key Laboratory of Organosilicon Material Technology of Zhejiang Province, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China

,

Li-Wen Xu∗

^aCollege of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China

^bKey Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, and Key Laboratory of Organosilicon Material Technology of Zhejiang Province, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China

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Abstract

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Abstract

Studies on the enantioselective transformation of silacyclobutanes (SCBs) have become an emerging topic in the recent decade, due to the feature of high ring strain, and manageable Si–C bond cleavage and formation. This short review summarizes the remarkable achievements in the asymmetric transition-metal-mediated reaction of silacyclobutanes and benzosilacyclobutanes, resulting in carbon- or silicon-stereogenic organosilanes with functional substituents.
1 Introduction
2 Asymmetric Transition-Metal-Catalyzed Ring Expansion Reaction
3 Asymmetric Transition-Metal-Catalyzed Ring-Opening Reaction
4 Conclusion and Outlook

Key words

silacyclobutanes - benzosilacyclobutenes - transition metal - silicon–carbon cleavage and formation - silicon-stereogenic - organosilicon - ring-opening - ring expansion

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References

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