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Synthesis 2023; 55(05): 826-836
DOI: 10.1055/a-1976-4931
DOI: 10.1055/a-1976-4931
paper
XantPhos Pd-G3 as an Efficient Catalyst: Microwave-Assisted C–S Cross-Coupling Reaction in DMF
The present work has been done with the support from CNPq, Brazilian National Council for Scientific and Technological Development–Brazil and TWAS, the academy of sciences for the developing world. The authors N. L. C. D. and R. K. thank the ‘CNPq-TWAS fellow’. The author (N.L.C.D) thanks Fundação de Apoio ao Disinvolvement do Ensino, Ciência e Tecnologia do Estado de Mato Grosso do Sul (FUNDECT/Brazil - Chamada FUNDECT/CNPq N° 15/2014–PRONEM–MS and Chamada FUNDECT N° 06/2017–UNIVERSAL-MS) and the Conselho Nacional de Desenvolvimento Científico e Tecnológico (Chamada CNPq Nº 12/2017 - Bolsas de Produtividade em Pesquisa - PQ) for financial support and fellowship.
Abstract
Buchwald precatalyst (XantPhos Pd-G3) was employed for the first time in a C–S cross-coupling reaction involving 2-(4-bromophenyl)benzothiazole or 5-bromo-2,1,3-benzothiadiazole with various benzenethiols in DMF, K2CO3 as a base, under microwave irradiation at 80 °C, 200 W. Good to excellent yields of the desired products were obtained under microwave conditions. Other significant benefits of this synthetic approach are low catalyst loading, short reaction times, and eco-friendly conditions. Additionally, 29 compounds were successfully synthesized, some of which are new in this protocol.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1976-4931.
- Supporting Information
Publication History
Received: 20 October 2022
Accepted: 10 November 2022
Accepted Manuscript online:
10 November 2022
Article published online:
30 November 2022
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