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CC BY 4.0 · SynOpen 2023; 07(01): 1-7
DOI: 10.1055/a-2004-6344
DOI: 10.1055/a-2004-6344
paper
Virtual Collection Click Chemistry and Drug Discovery
Click-Type Synthesis of Homoconjugated Push–Pull Chromophores: Computational Investigation of Optical and Nonlinear Optical (NLO) Properties
This work was supported by Türkiye Bilimsel ve Teknolojik Araştirma Kurumu (TUBITAK) under the grant no. 218Z126. CD also acknowledges the financial support provided by the GEBIP Award of the Turkish Academy of Sciences.
Abstract
Homoconjugated push–pull chromophores were obtained by an efficient, click-type formal [2+2] cycloaddition. With these short synthetic transformations, complex chromophore structures were achieved in a single step without any by-product formation. Significant second-order optical nonlinearities have been calculated for the synthesized compounds.
Key words
triazene - nonlinear optics - [2+2] cycloaddition - homoconjugation - donor–acceptor systems - intramolecular charge transferSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2004-6344.
- Supporting Information
Publication History
Received: 07 December 2022
Accepted after revision: 29 December 2022
Accepted Manuscript online:
29 December 2022
Article published online:
24 January 2023
© 2022. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/)
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