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Synthesis 2023; 55(18): 2896-2910
DOI: 10.1055/a-2004-6485
DOI: 10.1055/a-2004-6485
short review
Special Issue Electrochemical Organic Synthesis
Asymmetric Organic Electrochemistry Catalyzed by Transition Metals
This work was supported by the Thousand Young Talents Plan of China (Prof. Q. Lu), the National Natural Science Foundation of China (No. 22271227), and Wuhan University.
Abstract
Asymmetric catalysis is one of the most important areas of organic synthetic chemistry. In recent years, with the revival of organic electrochemistry, scientists have begun to try to combine asymmetric catalysis with electrochemistry to build valuable chiral molecules. In this review, we focus on examples of organic electrochemistry catalyzed by transition metals. According to the classification of the interaction of the catalyst with the substrate, we can divide them into two categories: (1) transition metal catalysts as chiral Lewis acids; (2) transition metal catalysts that construct chiral molecules by interacting with substrates through oxidative addition/reductive elimination.
1 Introduction
2 Electrochemical Asymmetric Lewis Acid Catalysis
3 Electrochemical Asymmetric Transition Metal Catalysis
4 Conclusion
Key words
electrosynthesis - electrochemical asymmetric catalysis - transition metal catalysis - Lewis acid catalysis - oxidative addition - reductive eliminationPublication History
Received: 07 December 2022
Accepted after revision: 29 December 2022
Accepted Manuscript online:
29 December 2022
Article published online:
02 February 2023
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