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CC BY 4.0 · SynOpen 2023; 07(01): 65-68
DOI: 10.1055/a-2024-1382
DOI: 10.1055/a-2024-1382
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Langlois Reagent: An Efficient Trifluoromethylation Reagent
![](https://www.thieme-connect.de/media/10.1055-s-00032269/202301/lookinside/thumbnails/so-2022-d0076-spot_10-1055_a-2024-1382-1.jpg)
Abstract
Key words
Langlois reagent - trifluoromethylation - free radical - fluoroorganic synthesis - sodium trifluoromethanesulfinate or sodium triflinatePublikationsverlauf
Eingereicht: 15. Dezember 2022
Angenommen nach Revision: 01. Februar 2023
Accepted Manuscript online:
01. Februar 2023
Artikel online veröffentlicht:
20. Februar 2023
© 2023. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/)
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References
- 1 Wang J, Sánchez-Roselló M, Aceña J, del Pozo C, Sorochinsky AE, Fustero S, Soloshonok VA, Liu H. Chem. Rev. 2014; 114: 2432
- 2 Li G, Zhang C, Song C, Ma Y. Beilstein J. Org. Chem. 2018; 14: 155
- 3a Charpentier J, Frü N, Togni A. Chem. Rev. 2014; 115: 650
- 3b Zhang C. Adv. Synth. Catal. 2014; 356: 2895
- 3c Mudarraa AL, de Salinasa SM, Temprano MH. P. Synthesis 2019; 51: 2809
- 3d Haiwen X, Zhenzhen Z, Yewen F, Lin Z, Chaozhong L. Chem. Soc. Rev. 2021; 50: 6308
- 4 Mehta J, Aryal P, Reddy VP. Eur. J. Org. Chem. 2021; 13: 2018
- 5 Zha X, Wei A, Yang B, Li T, Li Q, Qiu D, Lu K. J. Org. Chem. 2017; 82: 9175
- 6a Tordeux M, Langlois B, Wakselman C. J. Org. Chem. 1989; 54: 2452
- 6b Langlois BR, Laurent E, Roidot N. Tetrahedron Lett. 1991; 32: 7525
- 7 Ji Y, Brueckl T, Baxter RD, Fujiwara Y, Seiple IB, Su S, Blackmond DG, Baran PS. Proc. Natl. Acad. Sci. U.S.A. 2011; 108: 14411
- 8 Li Z, Jiao L, Sun Y, He Z, Wei Z, Liao WW. Angew. Chem. Int. Ed. 2020; 59: 7266
- 9 Sun H, Cui G, Shang H, Cui B. J. Org. Chem. 2020; 85: 15241
- 10 Yu Q, Liu Y, Wan JP. Chin. Chem. Lett. 2021; 32: 3514
- 11 Kulthe AD, Mainkar PS, Akondi SM. Chem. Commun. 2021; 57: 5582
- 12 Louvel D, Souibgui A, Taponard A, Rouillon J, Mosbah MB, Moussaoui Y, Pilet G, Khrouz L, Monnereau C, Tlili A. Adv. Synth. Catal. 2021; 364: 139
- 13 Li H, Peng X, Nie L, Zhou L, Yang M, Li F, Hu J, Yao Z, Liu L. RSC Adv. 2021; 11: 38667
- 14 Tang L, Yang F, Zhang S, Lv G, Zhou Q, Zheng L. J. Org. Chem. 2022; 87: 7274
- 15 Thota P, Sheelam K, Kottawar S, Shivakumar K, Kaliyaperumal M, Yennam S, Behera M. Synlett 2022; 33: 1660
- 16 Cui J, Tong Y, Li Y. J. Org. Chem. 2022; 87: 16090