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Synthesis 2023; 55(14): 2143-2150
DOI: 10.1055/a-2044-9651
DOI: 10.1055/a-2044-9651
paper
One-Pot, Metal-Free Synthesis of Phenols from Arylboronic Acids and Subsequent Conversion with N-Hydroxyphthalimide Esters
The authors acknowledge the National Key Research and Development Program of China (No. SQ2017YFC170600), Key R & D plan (major innovation project) project of Shandong Province (No. 2021CXGC010510), and Shandong University of Traditional Chinese Medicine (2022043, 2022050) for financial support.
Abstract
A one-pot synthesis of phenyl esters between N-hydroxyphthalimide (NHP) esters derived from carboxylic acid and arylboronic acids is developed. This tandem reaction underwent mild conditions with a broad range of substrates scope (up to 27 examples) in good to excellent yields (up to 93% yield). The reaction can be easily scaled up, which thus pave the way for further applications in late-stage modification.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2044-9651.
- Supporting Information
Publication History
Received: 15 December 2022
Accepted after revision: 01 March 2023
Accepted Manuscript online:
01 March 2023
Article published online:
03 April 2023
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