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Synthesis 2023; 55(14): 2151-2158
DOI: 10.1055/a-2047-6742
DOI: 10.1055/a-2047-6742
paper
Polycyclic High-Density Cage Compounds via Cross Metathesis
Defense Research and Development Organisation (DRDO, NO. ARDB/01/1041849/M/1), New Delhi-India.
Abstract
The synthesis of various highly functionalized caged systems suitable as high energy density materials, which were assembled by utilization of an olefin cross-metathesis strategy, is reported. E-Selectivity was observed during the cross-metathesis by using Grubbs second generation catalyst (G-II) and N-tolyl Grubbs catalyst in most of the cross-metathesis products. The stereochemistry of the olefin formed during the cross-metathesis has been determined unambiguously by a single-crystal X-ray diffraction study.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2047-6742.
- Supporting Information
- CIF File
Publication History
Received: 15 December 2022
Accepted after revision: 06 March 2023
Accepted Manuscript online:
06 March 2023
Article published online:
12 April 2023
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