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Synthesis 2023; 55(16): 2487-2494
DOI: 10.1055/a-2065-5802
DOI: 10.1055/a-2065-5802
paper
Reductive Coupling of Sodium Sulfinates for the Synthesis of Thiosulfonates
We gratefully acknowledge the financial support of the ’Jiangsu Specially-Appointed Professors Program’, the Natural Science Foundation of Jiangsu Province (BK20210542).
Abstract
A reductive coupling reaction of sodium sulfinates for the synthesis of symmetrical/unsymmetrical thiosulfonates is developed. The reaction takes place in the presence of acetyl chloride and Hantzsch ester under mild conditions and exhibits broad functional group tolerance. Mechanistic studies suggest that a radical process is involved.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2065-5802.
- Supporting Information
Publication History
Received: 24 February 2023
Accepted after revision: 29 March 2023
Accepted Manuscript online:
29 March 2023
Article published online:
25 April 2023
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