Synthesis 2023; 55(16): 2537-2542
paper
Special Issue Honoring Prof. Guoqiang Lin’s Contributions to Organic Chemistry
Palladium/Azaphos-Catalyzed Asymmetric Suzuki–Miyaura Coupling
Yanxin Jiang
a
Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
,
Kwai Wun Cheng
a
Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
,
Haoyang Zhang
b
Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, P. R. of China
,
Zhiping Yang∗
a
Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
,
a
Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
› Author Affiliations We gratefully acknowledge the Research Grants Council of Hong Kong (GRF 12303422) and HKBU RC-Tier 2 Start-up Grant for financial support.
Dedicated to Professor Guo-Qiang Lin on the occasion of his 80th birthday
Abstract
A palladium-catalyzed asymmetric Suzuki–Miyaura coupling is described with a unique monophosphine ligand, Azaphos. This method provides a new ligand framework that could be used in asymmetric Suzuki–Miyaura coupling reactions to prepare the axially chiral compounds.
Key words
Suzuki–Miyaura coupling -
azaphos -
palladium -
axial chirality
Supporting Information
Supporting information for this article is available online at https://doi.org/10.1055/a-2069-4665.
Supporting Information
Publication History
Received: 23 February 2023
© 2023. Thieme. All rights reserved
Georg Thieme Verlag KG
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