Metal-Loaded Semiconductor-Photocatalysis of Alcohols for Selective Organic Synthesis: A Personal Account

Shogo Mori; Shu Sakurai; Hiroshi Naka; Susumu Saito

doi:10.1055/a-2124-4037

Synlett, Table of Contents

Synlett 2023; 34(20): 2361-2373
DOI: 10.1055/a-2124-4037

account

Special Issue Dedicated to Prof. Hisashi Yamamoto

Metal-Loaded Semiconductor-Photocatalysis of Alcohols for Selective Organic Synthesis: A Personal Account

Shogo Mori∗

^aIntegrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Chikusa-ku, Nagoya 464-8602, Japan

,

Shu Sakurai

^bGraduate School of Science, Nagoya University, Chikusa-ku, Nagoya 464-8602, Japan

,

Hiroshi Naka ∗

^cGraduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

^dDeuterium Science Research Unit, Center for the Promotion of Interdisciplinary Education and Research, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

,

Susumu Saito ∗

^aIntegrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Chikusa-ku, Nagoya 464-8602, Japan

^bGraduate School of Science, Nagoya University, Chikusa-ku, Nagoya 464-8602, Japan

› Author Affiliations

Abstract

All articles of this category

Dedicated to Professor Hisashi Yamamoto on the occasion of his 80th birthday

Abstract

In this account, we review our research over the last decade on metal-loaded semiconductor-photocatalyzed organic transformations using alcohols. Different from many reactions using alcohols as mere sacrificial electron donors, our study has demonstrated alcohols as useful organic building blocks incorporated into value-added products. Besides such recollections of previous results, we briefly introduce our ongoing project involving photocatalytic C–C bond-forming reactions via the C–C bond scission of tertiary alcohols.

1 Introduction

2 Dehydroxylative Hydrogenolysis of Allylic Alcohols

3 Acceptorless Dehydrogenation of Activated/Unactivated Alcohols

4 N-Alkylation of Amines using Alcohols as Alkylating Agents

5 Summary and Outlook

Key words

semiconductors - photocatalysts - alcohols - dehydroxylative hydrogenolysis - dehydrogenation - N-alkylation - N-methylation - β-scission

Full Text

References

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