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CC BY 4.0 · SynOpen 2023; 07(04): 466-485
DOI: 10.1055/a-2167-8298
DOI: 10.1055/a-2167-8298
graphical review
Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation
Financial support from the National Natural Science Foundation of China [22271250 (T.Z.), 21925109 (B.-F.S.)], Zhejiang Provincial Natural Science Foundation [LD22B030003 (B.-F.S.)], the National Key Research and Development Program of China [2021YFF0701600 (B.-F.S.)], the Fundamental Research Funds for the Central Universities [226-2022-00224 (B.-F. S.), 226-2022-00175 (T.Z.)], the Open Research Fund of School Chemistry and Chemical Engineering, Henan Normal University and the Center of Chemistry for Frontier Technologies of Zhejiang University is gratefully acknowledged.
Abstract
Transition-metal-catalyzed enantioselective C–H activation provides a straightforward strategy to synthesize chiral molecules from readily available sources. In this graphical review, we summarize the progress on half-sandwich d6-metal (CoIII, RhIII, IrIII, RuII)-catalyzed enantioselective C–H functionalization reactions. The review is categorized according to the type of metal catalyst and chiral ligand employed. Representative enantio-determining models and catalytic cycles are presented.
Keywords
enantioselectivity - C–H activation - half-sandwich - cobalt - rhodium - iridium - ruthenium - chiral carboxylic acidPublication History
Received: 25 July 2023
Accepted after revision: 04 September 2023
Accepted Manuscript online:
06 September 2023
Article published online:
05 October 2023
© 2023. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/)
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During the preparation of this graphical review, several reports on this topic appeared highlighting the importance of these chiral catalysts, see: