Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation

Pu-Fan Qian; Jun-Yi Li; Yi-Bo Zhou; Tao Zhou; Bing-Feng Shi

doi:10.1055/a-2167-8298

SynOpen, Inhaltsverzeichnis

CC BY 4.0 · SynOpen 2023; 07(04): 466-485
DOI: 10.1055/a-2167-8298

graphical review

Half-Sandwich d⁶-Metal (Co^III, Rh^III, Ir^III, Ru^II)-Catalyzed Enantioselective C–H Activation

Pu-Fan Qian ‡

^aCenter of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China

,

Jun-Yi Li‡

^aCenter of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China

,

Yi-Bo Zhou‡

^aCenter of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China

,

Tao Zhou∗

^aCenter of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China

,

Bing-Feng Shi ∗

^aCenter of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China

^bCollege of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, 450001, P. R. of China

^cSchool of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, P. R. of China

^dCollege of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. of China

^eSchool of Biotechnology and Health Sciences, Wuyi University, Jiangmen, Guangdong 529020, P. R. of China

› Institutsangaben

Abstract

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Abstract

Transition-metal-catalyzed enantioselective C–H activation provides a straightforward strategy to synthesize chiral molecules from readily available sources. In this graphical review, we summarize the progress on half-sandwich d⁶-metal (Co^III, Rh^III, Ir^III, Ru^II)-catalyzed enantioselective C–H functionalization reactions. The review is categorized according to the type of metal catalyst and chiral ligand employed. Representative enantio-determining models and catalytic cycles are presented.

Keywords

enantioselectivity - C–H activation - half-sandwich - cobalt - rhodium - iridium - ruthenium - chiral carboxylic acid

Volltext

Referenzen

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During the preparation of this graphical review, several reports on this topic appeared highlighting the importance of these chiral catalysts, see:

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