Synthesis 2024; 56(11): 1687-1694
DOI: 10.1055/a-2200-5332
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New Trends in Organic Synthesis from Chinese Chemists

Electrochemical Hydro- and Deuterocarboxylation of Allenes

Cheng-Lin Ding
,
Jun-Song Zhong
,
Hong Yan
,
Ke-Yin Ye
Financial support from the National Natural Science Foundation of China (No. 22171046), Hundred-Talent Project of Fujian (No. 50021113), and Fuzhou University (No. 510841) is gratefully acknowledged.


Abstract

Electrochemical hydrocarboxylation and deuterocarboxylation of allenes and carbon dioxide were achieved with H2O and D2O, respectively. This reaction generally affords good to excellent regioselectivity in the formation of diverse carboxylic acids.

Supporting Information



Publication History

Received: 14 September 2023

Accepted after revision: 27 October 2023

Accepted Manuscript online:
27 October 2023

Article published online:
27 November 2023

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