Synlett 2024; 35(16): 1861-1871
Pd-Catalyzed Oxidative Functionalization of Alkenes, Arenes, and 1,3-Dienes Using Molecular Oxygen as the Terminal Oxidant
,
This work was supported in part by the ‘Development of Innovative Catalytic Processes for Organosilicon Functional Materials’ project (PL: Kazuhiko Sato) from the New Energy and Industrial Technology Development Organization (NEDO). This research was also supported by the Kansai University Grant-in-Aid for progress of research in graduate course, 2023.
Abstract
This Account presents palladium-complex-catalyzed oxidative couplings mainly developed by the author’s group, including oxidative amination and silylation of terminal alkenes, direct oxidative arylation of aromatic compounds, and oxidative difunctionalization of 1,3-dienes. The catalytic cycles in these representative reactions feature re-oxidation of the palladium species with molecular oxygen as the terminal oxidant. Varying the combination of palladium catalyst and re-oxidant enables the formation of a variety of bonds through dehydrogenative cross-coupling reactions.
1 Introduction
2 Oxidative Amination of Terminal Alkenes
3 Direct Oxidative Arylation of Aromatic Compounds
4 Oxidative Silylation of Terminal Alkenes
5 Oxidative Difunctionalization of 1,3-Dienes
6 Conclusions and Perspectives
Key words
palladium -
oxidative coupling -
alkene -
1,3-diene -
re-oxidation -
aerobic oxidation
Publikationsverlauf
Eingereicht: 17. November 2023
© 2024. Thieme. All rights reserved
Georg Thieme Verlag KG
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