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DOI: 10.1055/a-2280-0055
Electrochemical Generation of Ketyl Radicals and Their Applications
Financial support from the National Natural Science Foundation of China (22171015 and 22271009), the Beijing Municipal Natural Science Foundation (2222003), and the Beijing Municipal Education Committee Project (KZ202110005003, KM202110005006) is gratefully acknowledged.
Abstract
Ketyl radicals display new reactivities beyond the intrinsic electrophilicity of carbonyls. Recent progress in organic electrosynthesis has fueled the generation and utilization of ketyl radicals under ‘greener’ conditions. This graphical review summarizes these electrochemical advancements into three major categories: cross-pinacol couplings, coupling of carbonyls with alkyl radical precursors, and coupling of carbonyls with unsaturated systems (alkenes, alkynes, cyanoarenes, and N-heterocycles).
Publikationsverlauf
Eingereicht: 28. Januar 2024
Angenommen nach Revision: 01. März 2024
Accepted Manuscript online:
01. März 2024
Artikel online veröffentlicht:
18. März 2024
© 2024. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/)
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