The Difunctionalization of Alkenes Completed by DMTSM and CF₃SO₂Na without Metal Catalysts

Abstract

The electrophilic thiolation of alkenes initiated by DMTSM and the addition of CF₃SO₂Na in one pot has been developed. This reaction also can be extended to ArSO₂Na. This protocol features a good substrate scope, simple procedures, and mild reaction conditions and affords the desired products in moderate yields without metal catalysts.

Key words

DMTSM - CF₃SO₂Na - difunctionalization

Publication History

Received: 31 January 2024

Accepted after revision: 07 March 2024

Accepted Manuscript online:
07 March 2024

Article published online:
22 March 2024

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