A Nonbenzenoid 3D Nanographene Containing 5/6/7/8-Membered Rings

Pengcai Liu; Hao-Han Lv; Rui Xue; Xiao-Yu Tang; Xing-Yu Chen; Liping Qi; Xiao-Ye Wang

doi:10.1055/a-2291-8774

Organic Materials, Inhaltsverzeichnis

CC BY 4.0 · Organic Materials 2024; 06(02): 40-44
DOI: 10.1055/a-2291-8774

Soluble Graphene Nanoarchitectures

Short Communication

A Nonbenzenoid 3D Nanographene Containing 5/6/7/8-Membered Rings

Pengcai Liu

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

,

Hao-Han Lv

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

,

Rui Xue

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

,

Xiao-Yu Tang

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

,

Xing-Yu Chen

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

,

Liping Qi

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

,

Xiao-Ye Wang

^aState Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94, Tianjin 300071, P. R. of China

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Abstract

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Abstract

Nanographenes (NGs) have attracted continuous attention in recent years owing to their opened bandgaps and optoelectronic applications. Especially, nonbenzenoid NGs containing non-six-membered rings have been developed rapidly due to their unique structures and properties. In this work, we employ nonbenzenoid acepleiadylene (APD) and the cyclooctatetraene (COT) moiety to construct the first three-dimensional (3D) NG containing 5/6/7/8-membered rings in one molecule (COT-APD). The calculated results prove that COT-APD has a saddle-like configuration similar to that of other COT-type molecules. Each APD segment in COT-APD keeps the inherent aromaticity of the APD moiety. Compared with other COT-type molecules, COT-APD shows a narrower bandgap, which indicates the superiority of APD in bandgap regulation. Furthermore, four reversible reductive waves are observed in electrochemical characterizations, demonstrating the excellent electron-accepting capability of COT-APD.

Key words

nanographenes - nonbenzenoid arenes - cyclooctatetraene - acepleiadylene

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References and Notes

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