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Synthesis
DOI: 10.1055/a-2518-0987
DOI: 10.1055/a-2518-0987
paper
Bürgenstock Special Section 2023 – Future Stars in Organic Chemistry
EDA Complexation of Two Donor Molecules Initiating Radical Cation Cyclizations
Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) –GRK 2678-437785492 (J.K, L.L.), CRC 1459 Intelligent Matter–Project-ID 433682494 (M.U.). Fonds der Chemischen Industrie (Liebig Fellowship, L.N., R.J., Kekule Fellowship L.L.).
Abstract
In this study, a catalyst-free EDA complexation of two donor molecules using an acidic solvent is presented. The electron-rich aromatic compound (E)-anethole is slowly protonated by the solvent hexafluoroisopropanol (HFIP), leading to the rapid formation of a photoactive EDA complex between a protonated (E)-anethole and another (E)-anethole molecule. This resulting EDA complex initiates radical chain cyclization reactions under green light irradiation.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2518-0987.
- Supporting Information
Publikationsverlauf
Eingereicht: 13. Dezember 2024
Angenommen nach Revision: 16. Januar 2025
Accepted Manuscript online:
16. Januar 2025
Artikel online veröffentlicht:
05. März 2025
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