Photoredox-Catalyzed Transfer Thiobenzoyloxylation of Styrenes Using Oxime-Based Surrogates

Abstract

Based on our previous work, a photoredox-catalyzed transfer thiobenzoyloxylation of styrenes using oxime-based surrogates is reported. The redox-neutral protocol enables regioselective vicinal C–S and C–O bond formation under mild conditions. Mechanistic studies support a radical–polar crossover pathway.

Keywords

Difunctionalization - Oximes - Photoredox catalysis - Single electron transfer - Transfer reactions

Publication History

Received: 16 January 2026

Accepted after revision: 04 February 2026

Accepted Manuscript online:
04 February 2026

Article published online:
17 February 2026

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