o-Benzenedisulfonimide
as a Soft, Efficient, and Recyclable Catalyst for the Acylation
of Alcohols, Phenols, and Thiols under Solvent-Free Conditions: Advantages
and Limitations

Margherita Barbero; Silvano Cadamuro; Stefano Dughera; Paolo Venturello

doi:10.1055/s-0028-1083215

PAPER

o-Benzenedisulfonimide as a Soft, Efficient, and Recyclable Catalyst for the Acylation of Alcohols, Phenols, and Thiols under Solvent-Free Conditions: Advantages and Limitations

Margherita Barbero*, Silvano Cadamuro, Stefano Dughera, Paolo Venturello
Dipartimento di Chimica Generale e Chimica Organica dell’Università, Università di Torino, Via P. Giuria 7, 10125 Torino, Italy
Fax: +39(11)6707642; e-Mail: margherita.barbero@unito.it;

Abstract

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Abstract

o-Benzenedisulfonimide turns out to be a highly efficient Brønsted acid catalyst for the acylation of a number of alcohols, phenols, and thiols under a metal- and solvent-free procedure; reaction conditions are mild and yields very good. After the workup, the catalyst can be easily recovered and purified, ready to be reused, with economic and ecological advantages.

Key words

o-benzenedisulfonimide - acid catalysis - recyclable catalyst - acylation reaction

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Referenzen

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