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Synthesis 2008(23): 3797-3800
DOI: 10.1055/s-0028-1087225
DOI: 10.1055/s-0028-1087225
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
An Efficient Oxidation of Element-Containing Propargyl Alcohols and Acetylenic γ-Diols by 2-Iodoxybenzoic Acid (IBX)
Further Information
Received
14 July 2008
Publication Date:
06 November 2008 (online)
Publication History
Publication Date:
06 November 2008 (online)
Abstract
An efficient and convenient procedure for the oxidation of acetylenic alcohols and diols by o-iodoxybenzoic acid (IBX) is reported. Simple heating of the corresponding alcohol with a suspension of IBX in acetone or tetrahydrofuran leads to the silicon(germanium)-containing propynals or γ-hydroxypropynals in high yields.
Key words
propargyl alcohols - acetylenic diols - oxidation - IBX - propynals
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