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Synthesis 2009(9): 1578-1581
DOI: 10.1055/s-0028-1088026
DOI: 10.1055/s-0028-1088026
PSP
© Georg Thieme Verlag
Stuttgart ˙ New York
Conversion of Primary Alcohols and Aldehydes into Methyl Esters by Ruthenium-Catalysed Hydrogen Transfer Reactions
Weitere Informationen
Received
5 December 2008
Publikationsdatum:
14. April 2009 (online)
Publikationsverlauf
Publikationsdatum:
14. April 2009 (online)
Abstract
Alcohols and aldehydes are oxidised to the corresponding methyl esters by reaction with methanol in the presence of crotononitrile as a hydrogen acceptor using a catalyst combination of Ru(PPh3)3(CO)H2 with xantphos.
Key words
alcohols - esters - ruthenium - catalysis - hydrogen transfer
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