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Synthesis 2009(22): 3791-3796
DOI: 10.1055/s-0029-1217010
DOI: 10.1055/s-0029-1217010
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of (E)-Stilbenes and (E,E)-1,4-Diphenylbuta-1,3-diene Promoted by Boron Trifluoride-Diethyl Ether Complex
Further Information
Received
4 May 2009
Publication Date:
23 September 2009 (online)
Publication History
Publication Date:
23 September 2009 (online)
Abstract
An efficient, simple, and practical method has been developed to regioselectively synthesize (E)-stilbenes and (E,E)-1,4-diphenylbuta-1,3-diene in good to excellent yields in the presence of boron trifluoride-diethyl ether complex as a catalyst in a short reaction (30-60 s) at room temperature.
Key words
boron trifluoride-diethyl ether complex - (E)-stilbenes - (E,E)-1,4-diphenylbuta-1,3-diene - ketones - regioselectivity
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References
Please see the experimental section for the reaction procedure.