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Synthesis 2010(3): 465-469
DOI: 10.1055/s-0029-1218582
DOI: 10.1055/s-0029-1218582
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Dicationic Acridinophane: Optical and Electrochemical Studies
Weitere Informationen
Received
15 September 2009
Publikationsdatum:
27. November 2009 (online)
Publikationsverlauf
Publikationsdatum:
27. November 2009 (online)
![](https://www.thieme-connect.de/media/synthesis/201003/lookinside/thumbnails/10.1055-s-0029-1218582-1.jpg)
Abstract
The synthesis of some novel dicationic acridinophanes has been achieved via an N-alkylation route using benzimidazole, imidazole and benzotriazole as building units. UV-Visible studies revealed the absence of ground-state charge-transfer interactions between the acridine and imidazolium moieties. Electrochemical studies showed that the imidazolium and acridine units modify the characteristic redox properties of dicationic acridinophanes.
Key words
cationic - dicationic - cyclophane - acridine - macrocycle - receptor
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