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Synthesis 2010(4): 661-665
DOI: 10.1055/s-0029-1218612
DOI: 10.1055/s-0029-1218612
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane
Weitere Informationen
Received
23 July 2009
Publikationsdatum:
16. Dezember 2009 (online)
Publikationsverlauf
Publikationsdatum:
16. Dezember 2009 (online)
![](https://www.thieme-connect.de/media/synthesis/201004/lookinside/thumbnails/10.1055-s-0029-1218612-1.jpg)
Abstract
Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPh3)4 or Pd(dba)2 as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-dienes in good to high yields.
Key words
Baylis-Hillman acetates - allyltributylstannane - bis-π-allylpalladium - 1,5-diene - allylation
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