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Synthesis 2010(10): 1639-1644
DOI: 10.1055/s-0029-1218724
DOI: 10.1055/s-0029-1218724
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds
Further Information
Received
11 February 2010
Publication Date:
06 April 2010 (online)
Publication History
Publication Date:
06 April 2010 (online)
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Abstract
The synthesis of podands with cyanuric or isocyanuric acid cores and oligoethyleneoxy pendant arms exhibiting terminal triple bonds or brominated triple bonds is reported. The starting material for cyanuric acid derived podands is commercially available cyanuric acid, while the isocyanuric derivatives are obtained by thermal isomerization of the corresponding cyanurates.
Key words
podands - cyanurates - alkynes - isomerization - heterocycles
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