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Synthesis 2010(11): 1787-1792
DOI: 10.1055/s-0029-1218764
DOI: 10.1055/s-0029-1218764
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Spherical Polyols from Itaconic Acid
Further Information
Received
22 January 2010
Publication Date:
29 April 2010 (online)
Publication History
Publication Date:
29 April 2010 (online)
Abstract
The Diels-Alder reaction of some bromo derivatives of the itaconic acid with cyclopenta-1,3-diene gave a simple access to precursors of spherical polyols of synthetic interest.
Key words
bicyclic compounds - Diels-Alder reaction - ozonolysis - stereoselective synthesis - protecting groups
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References
X-ray crystallography: CCDC-767345 (for endo-4) and CCDC-767346 (for 10) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(1223)336033; or e-mail: deposit@ccdc.cam.ac.uk].