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Synthesis 2010(19): 3315-3318
DOI: 10.1055/s-0030-1257866
DOI: 10.1055/s-0030-1257866
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Pyridine 2,6-Dicarboxylic Acid as a Bifunctional Organocatalyst for Hydrophosphonylation of Aldehydes and Ketones in Water
Further Information
Received
10 May 2010
Publication Date:
22 July 2010 (online)
Publication History
Publication Date:
22 July 2010 (online)
Abstract
A novel organocatalytic, direct synthesis of α-hydroxy phosphonates via reaction of aldehydes and ketones with trimethylphosphite in the presence of catalytic amounts of pyridine 2,6-dicarboxylic acid in water is reported. The method is simple, cost-effective and environmentally benign.
Key words
α-hydroxy phosphonates - organocatalyst - pyridine 2,6-dicarboxylic acid - nucleophilic addition - water
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